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Palladium chloride-catalyzed reductive cleavage of benzylic acetal, ketal and ether compounds with triethylsilane

โœ Scribed by Mirza-Aghayan, M.; Boukherroub, R.; Rahimifard, M.; Zadmard, R.


Book ID
118774612
Publisher
Iranian Chemical Society
Year
2011
Tongue
English
Weight
203 KB
Volume
8
Category
Article
ISSN
1735-207X

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We have found that-olefin-palladium chloride complex is carbonylated to give 8-chloro acyl chloride.\* In addition, ve have found that metallic palladium ia a versatile catalyst for carbonylation of various olefinic compounds. For example, simple olafins and nonconjugated cyuloolefins4 can be conver