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Palladium-Catalyzed Tetrakis(dimethylamino)ethylene-Promoted Reductive Coupling of Aryl Halides.

✍ Scribed by Manabu Kuroboshi; Yoko Waki; Hideo Tanaka

Publisher
John Wiley and Sons
Year
2003
Weight
114 KB
Volume
34
Category
Article
ISSN
0931-7597

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Unsymmetrical Biaryls by Palladium-Catal
Unsymmetrical Biaryls by Palladium-Catalyzed Coupling of Aryl Halides with Internal Reduction
✍ Gedu Satyanarayana; Martin E. Maier πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 476 KB

## Abstract Aryl bromides containing a (1,4,5,6‐tetrahydro‐6‐oxopyridin‐3‐yl)methyl substituent can be coupled with aryl halides yielding unsummetrical biaryls. In the course of this process, the cyclic enamide is oxidized to the 2(1__H__)‐pyridinone. The reaction proceeds by a six‐membered pallada