Palladium-catalyzed telomerization of dienes and tertiary allylic amines. A novel reaction involving cleavage of the carbon-nitrogen bond

A novel preparative method for homo- and

A novel preparative method for homo- and heteroannular conjugated dienes in decalin derivatives by the palladium-catalyzed regioselective elimination reaction of allylic carbonates under mild conditions

✍ Tadakatsu Mandai; Takaji Matsumoto; Yoshiki Nakao; Hisami Teramoto; Mikio Kawada 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 253 KB

## Homoannular conjugated dienes in decalin systems can be prepared by the palladiumcatalyzed elimination reaction of a-allylic carbonates, and heteroannular dienes are obtained from /.%allylic carbonates. Both homoannular and heteroannular conjugated dienes in decalin systems are present in a num