✦ LIBER ✦
Palladium catalyzed synthesis of tertiary allylamines. Utilization of α-nitro olefins as allylic nitro compounds
✍ Scribed by Rui Tamura; Koji Hayashi; Yoshiki Kai; Daihei Oda
- Book ID
- 104233825
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 251 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Reaction of a-nitro olefins with secondary amines in the presence of palladium(O) catalyst affords allylic amines. a-Nitro olefins are easily prepared in good yields by numerous procedures 1 and have proven to be versatile synthetic intermediates. 2 Meanwhile, allylic nitro compounds, the isomer of a-nitro olefins, have been demonstrated to be