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Palladium-catalyzed synthesis of substituted cyclopentadienes and indenes from allylic esters

โœ Scribed by Jean-Claude Fiaud; Bernard Denner; Jean-Luc Malleron

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
543 KB
Volume
291
Category
Article
ISSN
0022-328X

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The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this me