𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Palladium-catalyzed synthesis of allylic thioacetates. A convenient access to allylic thiols

✍ Scribed by Sunil Divekar; Mohamed Safi; Mohamed Soufiaoui; Denis Sinou

Book ID
104209297
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
350 KB
Volume
55
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis

Palladium(O)-catalyzed alkylation of various allylic acetates and carbonates by potassium thioacetate allowed an easy access to allylic thioacetates in rather good yields. The reaction was regioselective with substitution at the less hindered side of the intermediate z-allyi system, and diastereoselcctive with net retention of configuration.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Palladium(0) Cataly
ChemInform Abstract: Palladium(0) Catalyzed Enantioselective Rearrangement of O-Allylic Thiocarbamates to S-Allylic Thiocarbamates: Asymmetric Synthesis of Allylic Thiols.
✍ Achim Boehme; Hans-Joachim Gais πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v