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Palladium-Catalyzed Stereospecific Synthesis of 2,6-Disubstituted Tetrahydropyrans: 1,3-Chirality Transfer by an Intramolecular Oxypalladation Reaction

✍ Scribed by Kawai, Nobuyuki; Lagrange, Jean-Marie; Ohmi, Masashi; Uenishi, Jun'ichi


Book ID
120916924
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
204 KB
Volume
71
Category
Article
ISSN
0022-3263

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✍ Nobuyuki Kawai; Ryuzou Abe; Mika Matsuda; Jun'ichi Uenishi πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 56 KB πŸ‘ 1 views

Synthesis of Chiral 1-Substituted Tetrahydroisoquinolines by the Intramolecular 1,3-Chirality Transfer Reaction Catalyzed by Bi(OTf)3. -Treatment of chiral amines of type (I), (III), and (V) with Bi(OTf)3 results in formation of optically active tetrahydroisoquinolines. The (E)/(Z) configuration of