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Palladium-catalyzed rearrangement of α-cyanoallylic acetates application to a new synthetic method for furans

✍ Scribed by Tadakatsu Mandai; Susurnu Hashio; Jiso Goto; Mikio Kawada

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 204 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)90494-0

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✦ Synopsis

Various types of a-cyanoallylic acetates were undergone the palladium-catalyzed rearrangement to give the Y-acetoxy-u,B-unsaturated nitriles in high yields. These rearranged acetates were conveniently transformed into the furan derivatives often encountered in natural products by the reduction using diisobutylaluminum hydride.

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