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Palladium-catalyzed reactions: stereoselective synthesis of substituted cyclopropanes related to chrysanthemic acid. A simple route to cis-chrysanthemonitrile

โœ Scribed by Genet, Jean Pierre; Piau, Frederique


Book ID
125989879
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
609 KB
Volume
46
Category
Article
ISSN
0022-3263

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An improved procedure for the efficient synthesis of I~-halobutenolides was developed. The Pd(0)catalyzed coupling reactions of 13-halobutenolides with terminal alkynes or organozinc reagents, i.e., 1-alkenyl, aryl, and alkyl zinc reagents, to afford 13-substituted butenolides were carefully studied