Palladium catalyzed reactions of propionate homoemolate. Arylation, vinylation, and acylation

✍ Scribed by Eiichi Nakamura; Isao Kuwajima

• Book ID: 104218061
• Publisher: Elsevier Science
• Year: 1986
• Tongue: French
• Weight: 245 KB
• Volume: 27
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)83947-7

✦ Synopsis

Zinc homoenolate of alkyl propionate undergoes clean C-C bond forming reactions with aryl, vinyl, and acid halides in the presence of a palladium catalyst. Recent progress in homoenolate chemistry' has made possible some C-C bond forming reactions via metal homoenolates. 2--6 However, most of these reactions are Pd 20% DMA or D&t,