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Palladium-Catalyzed Reactions of Hypophosphorous Compounds with Allenes, Dienes, and Allylic Electrophiles: Methodology for the Synthesis of Allylic H -Phosphinates

✍ Scribed by Bravo-Altamirano, Karla; Abrunhosa-Thomas, Isabelle; Montchamp, Jean-Luc

Book ID
126860571
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
251 KB
Volume
73
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Palladium-Catalyzed
ChemInform Abstract: Palladium-Catalyzed Reactions of Hypophosphorous Compounds with Allenes, Dienes, and Allylic Electrophiles: Methodology for the Synthesis of Allylic H-Phosphinates.
✍ Karla Bravo-Altamirano; Isabelle Abrunhosa-Thomas; Jean-Luc Montchamp πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons βš– 60 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

One-step synthesis of Ξ±,Ξ²-unsaturated ke
One-step synthesis of Ξ±,Ξ²-unsaturated ketones by the reaction of enol acetates with allyl methyl carbonate catalyzed by palladium and tin compounds
✍ Jiro Tsuji; Ichiro Minami; Isao Shimizu πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 115 KB

Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet