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Palladium-catalyzed reactions of 1-phenylphospholene-1-oxides with aryl iodides and aryldiazonium salts

✍ Scribed by Pascal Desmazeau; Jean-Yves Legros; Jean-Claude Fiaud


Book ID
104259778
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
224 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis


l-Phenylphosphol-2-en-1-oxide la reacts with aryl iodides in the presence of ammonium formate and a catalytic amount of Pd(OAc)2 to give 3-aryl-1 -phenylphospholane-1-oxides 3, whereas 4-aryl-1 -phenylphosphol-2-en-1oxides 4 are obtained from l-phenylphosphol-3-en-l-oxide 2a under modified Heck reaction conditions (aryldiazonium salt, catalytic Pd(OAc)2).


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ChemInform Abstract: Palladium-Catalyzed
✍ P. DESMAZEAU; J.-Y. LEGROS; J.-C. FIAUD πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

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