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Palladium-Catalyzed Reaction of Propargyl Nucleophiles with α-Sulfonyl α,β-Unsaturated Ketones: A Single-Step Synthesis of Furo[3,4- c ] Heterocyclic Derivatives

✍ Scribed by Monteiro, Nuno; Balme, Geneviève


Book ID
118221848
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
175 KB
Volume
65
Category
Article
ISSN
0022-3263

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One-step synthesis of α,β-unsaturated ke
✍ Jiro Tsuji; Ichiro Minami; Isao Shimizu 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 115 KB

Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet