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Palladium-catalyzed reaction of nucleophiles with diacetates of allylic 1,1-diols

โœ Scribed by Xiyan Lu; Yujin Huang


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
319 KB
Volume
268
Category
Article
ISSN
0022-328X

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๐Ÿ“œ SIMILAR VOLUMES


Umpolung in allylic phosphonates. Regios
โœ Jingyang Zhu; Xiyan Lu ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 222 KB

Vinylic phosphonates with functional groups can be synthesized regioselectively by the reaction of acetoxy allylic phosphonates with soft carbon nucleophiles in the presence of bis(trimethylsilyl)acetamide (BSA) under palladium(O) catalysis with moderate to good yields.