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Palladium-catalyzed preparation of exo-aryl derivatives of the norbornane skeleton

✍ Scribed by A. Arcadi; F. Marinelli; E. Bernocchi; S. Cacchi; G. Ortar

Book ID
103225124
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
322 KB
Volume
368
Category
Article
ISSN
0022-328X

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## Abstract New, sterically demanding 1,3‐dialkylbenzimidazolium salts (**2a–c**) as __N__‐heterocyclic‐carbene precursors have been synthesized and characterized. The ortho position of aromatic aldehydes was directly and selectively arylated with aryl chlorides in the presence of a catalytic syste