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Palladium catalyzed polyhetero-Claisen rearrangement

✍ Scribed by Tamaru, Yoshinao; Kagotani, Musahiro; Yoshida, Zenichi

Book ID
127144801
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
387 KB
Volume
45
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Palladium(II)-catalyzed claisen rearrang
Palladium(II)-catalyzed claisen rearrangement of allyl vinyl ethers
✍ J.L van der Baan; F Bickelhaupt πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 258 KB

The Claisen rearrangement of ally1 vinyl ethers is catalyzed by PdCQ(CH3CN)Z. provided that alkyl substituents protect the vinyl ether double bond from coordination by the metal catalyst. [3,3]Sigmatropic rearrangements are very useful for the formation of C-C, C-O, C-N and C-S bonds. Besides the cl