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Palladium-Catalyzed Oxidative Cross-Coupling of N- Tosylhydrazones with Indoles: Synthesis of N- Vinylindoles

✍ Scribed by Zeng, Xiaobao; Cheng, Guolin; Shen, Jinhai; Cui, Xiuling

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## Abstract A variety of pyridine‐oxides undergoes a Pd‐catalyzed oxidative coupling with substituted indoles at the 3‐position.

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Scheme 1. Synthesis of conjugated enynes. EWG = electron-withdrawing group, Ts = p-toluenesulfonyl.