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Palladium-catalyzed intramolecular arylation of an anilide enolate, application to an efficient formal total synthesis of physovenine

โœ Scribed by Tony Y. Zhang; Hongbin Zhang


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
63 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


An expedient formal total synthesis of the calabar alkaloid physovenine was reported. The key step involves an oxindole synthesis via palladium-catalyzed intramolecular arylation of o-bromoanilide.


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