Palladium-Catalyzed Intramolecular Allylic Alkylation Reaction in Marine Natural Product Synthesis: Enantioselective Synthesis of (+)-Methyl Pederate, a Key Intermediate in Syntheses of Mycalamides

ChemInform Abstract: Palladium-Catalyzed

ChemInform Abstract: Palladium-Catalyzed Intramolecular Allylic Alkylation Reaction in Marine Natural Product Synthesis. Enantioselective Synthesis of (+)-Methyl Pederate, a Key Intermediate in Syntheses of Mycalamides.

✍ M. TOYOTA; M. HIROTA; Y. NISHIKAWA; K. FUKUMOTO; M. IHARA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 43 KB 👁 2 views

Palladium-Catalyzed Intramolecular Allylic Alkylation Reaction in Marine Natural Product Synthesis. Enantioselective Synthesis of (+)-Methyl Pederate, a Key Intermediate in Syntheses of Mycalamides. -The carbonate precursor (VIII) for the title key step, leading to lactone (IX), is effectively prepa