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Palladium-Catalyzed Insertion of Isocyanides into P(O)—H Bonds: Selective Formation of Phosphinoyl Imines and Bisphosphinoylaminomethanes.

✍ Scribed by Takayoshi Hirai; Li-Biao Han


Publisher
John Wiley and Sons
Year
2006
Weight
23 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Palladium-Catalyzed
✍ H. YAMASHITA; N. P. REDDY; M. TANAKA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

Palladium-Catalyzed Insertion of 1,2-and 1,4-Quinones into Si-Si Bonds and Its Application to the Modification of Si-Si-Bond-Containing Polymers. -The title reaction proceeds in the presence of palladium-phosphine catalysts, PdCl 2 (PEt 3 ) 2 is the most efficient, to give various 1,2-and 1,4-bis(s