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Palladium-catalyzed homogeneous coupling reactions of steroids with organostannanes

✍ Scribed by Rita Skoda-Földes; Zita Csákai; Lászlo Kollár; Judit Horváth; Zoltán Tuba


Book ID
118361562
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
483 KB
Volume
60
Category
Article
ISSN
0039-128X

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Palladium-catalyzed coupling of aryl tri
✍ Echavarren, Antonio M.; Stille, J. K. 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 984 KB

The palladium-catalyzed coupling reaction of aryl triflates with alkyl, vinyl, acetylenic, and aryl tin reagents in the presence of lithium chloride takes place in high yields under mild conditions. However, allyltrialkyltin reagents coupled in lower yields, and unselective transfer of the allyl gro