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Palladium-catalyzed enantioselective hydrogenation of 2-pyrones: evidence for competing reaction mechanisms

✍ Scribed by W.-R Huck; T Bürgi; T Mallat; A Baiker


Book ID
114046235
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
412 KB
Volume
219
Category
Article
ISSN
0021-9517

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A class of atropisomeric diphosphine ligands with a wide range of dihedral angles has been developed. X-ray study of the Pd(II) complexes of these ligands showed that as the bridge length increased, the dihedral angles and the ligand bite angles increased as well, while an excessive increase in brid