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Palladium-catalyzed electrochemical carbonylation of 2-amino-1-alkanols to oxazolidin-2-ones under very mild conditions

✍ Scribed by Isabella Chiarotto; Marta Feroci

Book ID: 104230564
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 72 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00497-x

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✦ Synopsis

A new procedure for an efficient synthesis of oxazolidin-2-ones was developed. 2-Amino-1-alkanols undergo oxidative carbonylation under atmospheric pressure of carbon monoxide at room temperature using Pd(II) catalyst in combination with its anodic recycling at a graphite electrode.

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