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Palladium-catalyzed double and monocarbonylation of phenyl iodide by methyl formate

✍ Scribed by Yves Castanet; André Mortreux; Francis Petit


Publisher
Elsevier Science
Year
1990
Weight
308 KB
Volume
63
Category
Article
ISSN
0304-5102

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By the palladium catalysis 2-carboethoxyethylzinc iodide reacts with aryl iodides and vinyl iodides or triflates to provide the coupling products (ethyl 3-arylpropionates and ethyl 4-pentenoates, respectively) in satisfactory yields. The similar coupling reaction is obserbed for the reaction with 3-