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Palladium Catalyzed Cross-Methylation of Bromoheterocycles with Intramolecularly Stabilized Dimethyl Indium Reagents.

✍ Scribed by Nimer Jaber; Herbert Schumann; Jochanan Blum


Publisher
John Wiley and Sons
Year
2004
Weight
158 KB
Volume
35
Category
Article
ISSN
0931-7597

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Palladium catalyzed cross-methylation of
✍ Nimer Jaber; Jochanan Blum; Herbert Schumann πŸ“‚ Article πŸ“… 2003 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 39 KB

## Abstract Although the intramolecularly stabilized [(3‐dimethylamino)propyl]dimethylaluminum (**1a**) fails to undergo palladium‐catalyzed cross‐coupling with bromopyridines and with bromofuran derivatives, the analogous gallium and indium reagent **1b** and **1c** smoothly cross‐methylate these