Palladium-catalyzed cross-coupling reaction: Direct allylation of aryl bromides with allyl acetate
β Scribed by Yuusaku Yokoyama; Sadao Ito; Yumi Takahashi; Yasuoki Murakami
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 203 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Pinacol boronates 2 couple efficiently with allyl acetates 1 in the presence of a palladium catalyst prepared in situ from PdCl 2 and TFP to give the coupled products 3 in moderate to good yields under mild conditions.
The reaction of ally1 bromides with ally1 tin reagents, catalyzed by palladium or zinc chloride gives cross-coupled products without allylic transpostion in the ally1 halide partner but with predominate allylic rearrangement from the tin partner. The synthesis of compounds containing the polyisopre
## Abstract For Abstract see ChemInform Abstract in Full Text.