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Palladium-Catalyzed Coupling Reactions of Bromo-Substituted Phenylphosphine Oxides: A Facile Route to Functionalized Arylphosphine Ligands.

โœ Scribed by Lijin Xu; Jun Mo; Colin Baillie; Jianliang Xiao


Publisher
John Wiley and Sons
Year
2004
Weight
209 KB
Volume
35
Category
Article
ISSN
0931-7597

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The reaction of 9-alkyl-9-BBNs with 1-bromo-i-phenylthioethene or (E)-and (Z)-2-bromo-lphenylthio-1-alkenes takes place readily in the presence of Pd(PPh& and sodium hydroxide to afford stereodefmed vinylic sulfides in excellent yields.