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Palladium-catalyzed coupling reactions of (.alpha.-ethoxyvinyl)trimethylstannane with vinyl and aryl triflates

✍ Scribed by Kwon, Hyok Boong; McKee, Blaine H.; Stille, J. K.


Book ID
126955544
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
726 KB
Volume
55
Category
Article
ISSN
0022-3263

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Palladium-catalyzed coupling of aryl tri
✍ Echavarren, Antonio M.; Stille, J. K. πŸ“‚ Article πŸ“… 1987 πŸ› American Chemical Society 🌐 English βš– 984 KB

The palladium-catalyzed coupling reaction of aryl triflates with alkyl, vinyl, acetylenic, and aryl tin reagents in the presence of lithium chloride takes place in high yields under mild conditions. However, allyltrialkyltin reagents coupled in lower yields, and unselective transfer of the allyl gro