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Palladium-catalyzed combustion of methane: Simulated gas turbine combustion at atmospheric pressure

✍ Scribed by Timothy Griffin; Wolfgang Weisenstein; Viktor Scherer; Martin Fowles


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
883 KB
Volume
101
Category
Article
ISSN
0010-2180

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✦ Synopsis


Atmospheric pressure tests were performed in which a palladium catalyst ignites and stabilizes the homogeneous combustion of methane. Palladium exhibited a reversible deactivation at temperatures above 75o"C, which acted to "self-regulate" its operating temperature. A properly treated palladium catalyst could be employed to preheat a methane/air mixture to temperatures required for ignition of gaseous combustion (ca. 800°C) without itself being exposed to the mixture adiabatic flame temperature. The operating temperature of the palladium was found to be relatively insensitive to the methane fuel concentration or catalyst inlet temperature over a wide range of conditions. Thus, palladium is well suited for application in the ignition and stabilization of methane combustion