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Palladium-catalyzed carbonylation of chlorobenzene in the presence of lewis acids

โœ Scribed by Noskov, Yurii G. ;Petrov, Edward S.

Publisher
Springer
Year
1998
Tongue
English
Weight
226 KB
Volume
64
Category
Article
ISSN
0133-1736

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Palladium-catalyzed conjugate reduction
Palladium-catalyzed conjugate reduction of ฮฑ-ฮฒ-unsaturated carbonyl compound with tributyltin hydride. The promoting influence of the presence of protonic or lewis acids.
โœ P. Four; P. Guibe ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 240 KB

Acetic acid or ZnC12 promote the palladium-catalyzed selective conjugate reduction of a,S-unsaturated carbonyl compounds with trlbutyltln hydride. Protonrc agents also promote the palladium-catalyzed hydrogenolysls of aryl ally1 ethers and ally1 carbamates.