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Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes: A Synergistic Effect of Dibenzalacetone on High Enantioselectivity

✍ Scribed by Ogasawara, Masamichi; Ikeda, Hisashi; Nagano, Takashi; Hayashi, Tamio


Book ID
126826417
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
33 KB
Volume
123
Category
Article
ISSN
0002-7863

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## Abstract We report herein the synthesis of novel chiral S,N‐heterobidentate thiourea‐oxazoline ligands and their application to palladium‐catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. Copper salts were found to play multiple roles in this reacti