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Palladium-Catalyzed asymmetric reduction of allylic esters with a new chiral monodentate ligand, 8-diphenylphosphino-8′-methoxy-1,1′-binaphthyl

✍ Scribed by Kaoru Fuji; Minoru Sakurai; Takayoshi Kinoshita; Takeo Kawabata

Book ID: 104259732
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 208 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01342-2

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✦ Synopsis

A new chiral monodentate ligand, 8-diphenylphosphino-8'-methoxy-1,1'-binaphthyl (8-MeO-MOP), was used for palladium-catalyzed reduction of allylic carbonates with formic acid. Various methylcarbonates of 3,3'-disubstituted allylic alcohols were converted to the corresponding optically active l-olefins with this ligand.

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