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Palladium-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones.

✍ Scribed by You-Qing Wang; Sheng-Mei Lu; Yong-Gui Zhou

Publisher
John Wiley and Sons
Year
2005
Weight
32 KB
Volume
36
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Asymmetric Allylic A
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Palladium-Catalyzed Asymmetric Allylic A
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## Abstract Palladium‐catalyzed asymmetric allylic alkylation of nonstabilized ketone enolates to generate quaternary centers has been achieved in excellent yield and enantioselectivity. Optimized conditions consist of performing the reaction in the presence of two equivalents of LDA as base, one e