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Palladium-Catalyzed Asymmetric Allylic Alkylation of meso- and dl -1,2-Divinylethylene Carbonate

✍ Scribed by Trost, Barry M.; Aponick, Aaron

Book ID
121416091
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
73 KB
Volume
128
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of Ketone Enolates.
✍ Barry M. Trost; Gretchen M. Schroeder πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 54 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of Ketone Enolates
✍ Barry M. Trost; Gretchen M. Schroeder πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 390 KB πŸ‘ 2 views

## Abstract Palladium‐catalyzed asymmetric allylic alkylation of nonstabilized ketone enolates to generate quaternary centers has been achieved in excellent yield and enantioselectivity. Optimized conditions consist of performing the reaction in the presence of two equivalents of LDA as base, one e