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Palladium-Catalyzed Asymmetric Allylation of Prochiral Nucleophiles: Synthesis of 3-Allyl-3-aryl Oxindoles.

โœ Scribed by Barry M. Trost; Mathias U. Frederiksen

Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of ฮฑ-Aryl Ketones
โœ Barry M. Trost; Gretchen M. Schroeder; Jesper Kristensen ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 115 KB ๐Ÿ‘ 1 views

The generation of quatenary chiral centers through catalytic asymmetric alkylation of ketone enolates has been the subject of investigation in recent years. [1] The palladiumcatalyzed asymmetric allylic alkylation (AAA) of prochiral nucleophiles represents one such strategy for the creation of quate