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Palladium-Catalyzed Amination of Aryl Bromides Utilizing Arene−Chromium Complexes as Ligands

✍ Scribed by Kamikawa, Ken; Sugimoto, Suguru; Uemura, Motokazu

Book ID
126429101
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
60 KB
Volume
63
Category
Article
ISSN
0022-3263

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Palladium-Catalyzed Amination of Aryl Br
Palladium-Catalyzed Amination of Aryl Bromides and Aryl Triflates Using Diphosphane Ligands: A Kinetic Study
✍ Yannick Guari; Gino P. F. van Strijdonck; Maarten D. K. Boele; Joost N. H. Reek; 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 224 KB 👁 2 views

Pd(PÀOÀP)(Ar)] complexes with ligands that have wide bite angles are active catalysts for the coupling of aniline derivatives with aryl triflates. Kinetic studies show that for these systems a fast equilibrium that involves coordination of the amine precedes the deprotonation, which is the rate-limi