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Palladium-Catalyzed Amination of Aryl Bromides Using Temperature-Controlled Microwave Heating.

โœ Scribed by Yiqian Wan; Mathias Alterman; Anders Hallberg


Book ID
111699512
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Amination of Aryl Br
โœ Yannick Guari; Gino P. F. van Strijdonck; Maarten D. K. Boele; Joost N. H. Reek; ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 224 KB ๐Ÿ‘ 2 views

Pd(Pร€Oร€P)(Ar)] complexes with ligands that have wide bite angles are active catalysts for the coupling of aniline derivatives with aryl triflates. Kinetic studies show that for these systems a fast equilibrium that involves coordination of the amine precedes the deprotonation, which is the rate-limi