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Palladium-catalyzed allylation of ketones and aldehydes via allyl enol carbonates

✍ Scribed by Jiro Tsuji; Ichiro Minami; Isao Shimizu

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 193 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)81772-4

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✦ Synopsis

Rearrangement of ally1 enol carbonates, prepared from ketones or aldehydes by trapping their enolates with ally1 chloroformate, to give e-ally1 ketones or aldehydes regioselectively is catalyzed by palladium-phosphine complexes under mild condtions.

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