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Palladium-Catalyzed 1,4-Difunctionalization of Butadiene To Form Skipped Polyenes

โœ Scribed by McCammant, Matthew S.; Liao, Longyan; Sigman, Matthew S.


Book ID
119993162
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
1019 KB
Volume
135
Category
Article
ISSN
0002-7863

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Butadienemonoxide reactswitbbighregioselectively withanhydridesto givepreferentially diestersof 2-buten-l,4-diolin presenceofpalladiumphosphinecomplexes. Reaction regioselectivityis shongly influencedby the nature of palladiumIigand,anhydrideand solvent. @ 1997Publishedby Elsevier Science Ltd. Reac