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Palladium catalysed regio and stereoselective reduction of Baylis-Hillman coupling products derived allylic acetates

✍ Scribed by Kandaswamy Pachamuthu; Yashwant D. Vankar

Book ID: 104259533
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 204 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01049-1

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✦ Synopsis

Acelates derived from a variety of the Baylis-Hillman products undergo reduction with HCOOH in the presence of Et.~N, Pd(OAc)2, and dppe (or tri-isepropylphosphite) to yield the corresponding trisubstituted Z-otefins in good yields displaying high regio and stereoselectivity.

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