๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Palladium catalysed reaction of oximes with butadiene

โœ Scribed by Raymond Baker; Malcolm S. Nobbs


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
111 KB
Volume
18
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis


The palladium complex catalysed reactions of butadiene with electrophiles and nucleophiles have been studied extensively, and the reactions with amines, alcohols, active methylenes, 1

Schiff bases, phenyl isocyanate and aldehydes are well reviewed . We have previously reported the formation of azo-compounds from the reaction of phenylhydrazones with butadiene in the presence of nickel and palladium complexes, was also observed 2 although for the latter catalyst some N-alkylation


๐Ÿ“œ SIMILAR VOLUMES


Reaction of tertiary allylic amines with
โœ Christina Moberg ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Tertiary allylic amines react with butadiene in the presence of palladium(O) with cleavage of the carbon-nitrogen bond of the allylic amine and formation of the unsaturated tertiarv amine 4. - In the course of our studies of nickel-catalyzed additions of secondary amines to butadiene,2 we found th

Control of selectivities in palladium-ca
โœ Jean-Yves Legros; Martial Toffano; Andrรฉ Boutros; Christophe Moinet; Jean-Claude ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 303 KB

2000 Acade ยดmie des sciences / E ยดditions scientifiques et me ยดdicales Elsevier SAS. Tous droits re ยดserve ยดs 1387 1609(00) 00104 3/REV Organic and organometallic synthesis / Synthe ยดse organique et organome ยดtallique

Reaction of aminoalcohols with butadiene
โœ J. David Umpleby ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 160 KB

## Abstract The aminoalcohols **1**, react with 2 equivalents of butadiene in the presence of catalytic quantities of bis (acetylacetonato)palladium/triphenylphosphine to give exclusively the corresponding __N__โ€octadienyl amninoalcohols. In the presence of excess butadiene, subsequent __O__โ€octadi

Beckmann reaction of oximes catalysed by
โœ Sosale Chandrasekhar; Kovuru Gopalaiah ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 81 KB

A variety of ketoximes undergo the Beckmann rearrangement when heated with 0.5 molar equiv. of chloral (neat melt/ 130ยฐC), to furnish the corresponding amides in excellent yields (generally 80-95%) after simple work-up. (Aromatic aldoximes dehydrated to the corresponding nitriles in excellent yields