Palladium catalysed reaction of oximes with butadiene
โ Scribed by Raymond Baker; Malcolm S. Nobbs
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 111 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The palladium complex catalysed reactions of butadiene with electrophiles and nucleophiles have been studied extensively, and the reactions with amines, alcohols, active methylenes, 1
Schiff bases, phenyl isocyanate and aldehydes are well reviewed . We have previously reported the formation of azo-compounds from the reaction of phenylhydrazones with butadiene in the presence of nickel and palladium complexes, was also observed 2 although for the latter catalyst some N-alkylation
๐ SIMILAR VOLUMES
Tertiary allylic amines react with butadiene in the presence of palladium(O) with cleavage of the carbon-nitrogen bond of the allylic amine and formation of the unsaturated tertiarv amine 4. - In the course of our studies of nickel-catalyzed additions of secondary amines to butadiene,2 we found th
2000 Acade ยดmie des sciences / E ยดditions scientifiques et me ยดdicales Elsevier SAS. Tous droits re ยดserve ยดs 1387 1609(00) 00104 3/REV Organic and organometallic synthesis / Synthe ยดse organique et organome ยดtallique
## Abstract The aminoalcohols **1**, react with 2 equivalents of butadiene in the presence of catalytic quantities of bis (acetylacetonato)palladium/triphenylphosphine to give exclusively the corresponding __N__โoctadienyl amninoalcohols. In the presence of excess butadiene, subsequent __O__โoctadi
A variety of ketoximes undergo the Beckmann rearrangement when heated with 0.5 molar equiv. of chloral (neat melt/ 130ยฐC), to furnish the corresponding amides in excellent yields (generally 80-95%) after simple work-up. (Aromatic aldoximes dehydrated to the corresponding nitriles in excellent yields