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Palladium-catalysed enantioselective hydrogenation of alkenoic acids. Role of isomerization

✍ Scribed by K. Borszeky; T. Mallat; A. Baiker


Book ID
110383346
Publisher
Springer US
Year
1999
Tongue
English
Weight
54 KB
Volume
59
Category
Article
ISSN
1011-372X

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✍ Henri Brunner; Irmgard Deml; Wolfgang Dirnberger; Bernd Nuber; Walter Reißer 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 691 KB

Allylation of 1,5-dimethylbarbituric acid (BS) with allyl ace-yl)phosphane with optically active primary amines. An optimisation of this ligand type showed that the substituents at tate using in situ catalysts of palladium(II) acetylacetonate and chiral phosphane imine ligands results in the enantio