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Palladium catalysed electrosynthesis using aryl trifluoromethanesulfonates (triflates). Synthesis of biaryls and aromatic carboxylic acids

✍ Scribed by Jutand, Anny; N�gri, Serge; Mosleh, Adil

Book ID
119945198
Publisher
The Royal Society of Chemistry
Year
1992
Tongue
English
Weight
289 KB
Volume
23
Category
Article
ISSN
0022-4936

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The electrochemical reduction of aryl and vinyl triflates in presence of an electron source, so that they react with electrophiles such as CO 2 . The reaction proceeds through an the presence of CO 2 and a catalytic amount of palladium results in the formation of aromatic and α,β-unsaturated activat