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Palladium catalysed asymmetric alkylation of benzophenone Schiff base glycine esters in ionic liquids

✍ Scribed by DAE HYUN KIM; JIN KYU IM; DAE WON KIM; MINSERK CHEONG; HOON SIK KIM; DEB KUMAR MUKHERJEE


Book ID
107584705
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2011
Tongue
English
Weight
256 KB
Volume
123
Category
Article
ISSN
0253-4134

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Double asymmetric synthesis: Palladium c
✍ J.P. Genet; N. Kopola; S. Juge; J. Ruiz-Montes; O.A.C. Antunes; S. Tanier πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 270 KB

A new double asymmetric induction in carbon-carbon bond formation is -achieved by the use of palladium chiral complexes in the alkylation of chiral Schiff bases1 derived from glycine. High diastereoisomeric excesses are obtained (90-999) using N.N-cyclohexylsulfamoylisobornyl derivatives and DIOP as