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Palladium and Platinum Units Grafted on the Periphery of Carbosilane Dendrimers

✍ Scribed by Mónica Benito; Oriol Rossell; Miquel Seco; Guillermo Muller; Juan I. Ordinas; Mercè Font-Bardia; Xavier Solans


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
212 KB
Volume
2002
Category
Article
ISSN
1434-1948

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✍ Carmela G. Arena; Felice Faraone; Claudia Graiff; Antonio Tiripicchio 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 297 KB 👁 1 views

The new mixed phosphane-phosphite ligands 1 and 2, derived from 3,3Ј-di-tert-butyl-2,2Ј-dihydroxy-5,5Ј-dimethoxybiphenyl and (S)-binaphthol, respectively, reacted with [Rh(COD)(THF) 2 ]CF 3 SO 3 to give the compounds [Rh(COD)(1)]CF 3 SO 3 and [Rh(COD)(2)]CF 3 SO 3 in which the ligands 1 and (S)-2 ar