P-V-Tequation of state of magnesiowüstite (Mg0.6Fe0.4)O
✍ Scribed by Yingwei Fei; Ho-kwang Mao; Jinfu Shu; Jingzu Hu
- Publisher
- Springer-Verlag
- Year
- 1992
- Tongue
- English
- Weight
- 615 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0342-1791
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✦ Synopsis
The lattice parameter of magnesiowfistite (Mgo.6Feo.~)O has been measured up to a pressure of 30 GPa and a temperature of 800 K, using an external heated diamond anvil cell and diffraction using X-rays from a synchrotron source. The experiments were conducted under quasi-hydrostatic condition, using neon as a pressure transmitting medium. The experimental P-V-T data were fitted to a thermal-pressure model with the isothermal bulk modulus at room temperature Kro = 157 GPa, (•Kro/OP)T=4, (~KT/OT),: -2.7(3)
• 10 .2 GPa/K, (~KT/OT),= -0.2(2)x 10 -2 GPa/K, and the Anderson-Grfineisen parameter 6T=4.3(5) above the Debye temperature. The data were also fitted to the Mie-Griineisen thermal equation of state. The least-squares fit yields the Debye temperature 0Do =500(20) K, the Griineisen parameter 7o= 1.50(5), and the volume dependence q = 1.1 (5). Both thermal-pressure models give consistent P-V--T relations for magnesiowfistite to 140 GPa and 4000 K. The P-V-T relations for magnesiowiistite were also calculate by using a modified high-temperature Birch-Murnaghan equation of state with a 6T of 4.3. The results are consistent with those calculated by using the thermal-pressure model and the Mie-Griineisen relation to 140 GPa and 3000 K.
📜 SIMILAR VOLUMES
The transport parameters of La Sr Co Fe O were determined by electrical conductivity relaxation and high 0.6 0.4 0.6 0.4 32d temperature coulometric titration experiments. The experimental response curves were analyzed in the frequency domain. The results obtained by both methods were in good agreem