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P-T Phase Diagram and Gold Valence State of the Perovskite-Type Mixed-Valence Compounds Cs2Au2X6 (X = Cl, Br, and I) under High Pressures

✍ Scribed by Kojima, N.; Hasegawa, M.; Kitagawa, H.; Kikegawa, T.; Shimomura, O.

Book ID
127179446
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
642 KB
Volume
116
Category
Article
ISSN
0002-7863

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P–T phase diagram and Au valence state o
P–T phase diagram and Au valence state of the perovskite-type Au mixed-valence complexes M2[AuIX2][AuIIIX4] (M=K, Rb, Cs; X=Cl, Br, I)
✍ N. Kojima; N. Matsushita πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 231 KB

M 2 [Au I X 2 ][Au III X 4 ] (M=K, Rb, Cs; X=Cl, Br, I) are perovskite-type gold mixed-valence complexes. In this review, we describe their structural P -T phase diagram, the pressure induced Au valence transition from the Au I, III state to the Au II one, which is coupled with a structural phase tr