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P-Stereogenic PCP Pincer–Pd Complexes: Synthesis and Application in Asymmetric Addition of Diarylphosphines to Nitroalkenes

✍ Scribed by Ding, Boqiang; Zhang, Zhenfeng; Xu, Yang; Liu, Yangang; Sugiya, Masashi; Imamoto, Tsuneo; Zhang, Wanbin


Book ID
121328942
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
637 KB
Volume
15
Category
Article
ISSN
1523-7060

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## Abstract Achiral P‐donor pincer‐aryl ruthenium complexes ([RuCl(PCP)(PPh~3~)]) 4c,d were synthesized __via__ transcyclometalation reactions by mixing equivalent amounts of [1,3‐phenylenebis(methylene)]bis[diisopropylphosphine] (2c) or [1,3‐phenylenebis(methylene)]bis[diphenylphosphine] (2d) and