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p -, o -η 4 -Benzoquinone and the Related η 6 -Hydroquinone, η 6 -Catechol Complexes of Pentamethylcyclopentadienyliridium: Synthesis, Structures, and Reactivity

✍ Scribed by Le Bras, Jean; Amouri, H.; Vaissermann, Jacqueline

Book ID
120830914
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
162 KB
Volume
17
Category
Article
ISSN
0276-7333

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✍ Marjolaine Doux; Louis Ricard; François Mathey; Pascal Le Floch; Nicolas Mézaill 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB 👁 1 views

## Abstract It has been shown that 2 equiv. of 2,3,5,6‐tetraphenylphosphinine (**2**) react with [Rh(COD)~2~][BF~4~] to yield the bis(η^1^‐phosphinine)Rh^I^ complex **6**, whose X‐ray crystal structure is presented. On the other hand, 2,6‐bis(trimethylsilyl)phosphinines **4** and **5** react with R