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p-Benzoquinone in aqueous solution: Stark shifts in spectra, asymmetry in solvent structure

✍ Scribed by Öhrn, Anders ;Aquilante, Francesco

Book ID
121215818
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
993 KB
Volume
9
Category
Article
ISSN
1463-9076

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Second order Stark shift of zero-field transitions in protonated and deuterated p-benzoquinones
✍ S.J. Sheng; M.A. El-Sayed; H.P. Trommsdorff 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 260 KB

The second order Stark effect on the zero-field transitions of the lowest triplet state of p-benzoquinone (-114 and -de) in a host of pdibromobenzene have been measured and compared. The electric field shifts of the microwave transitions of the perdeuterated compound are 1.9 + 0.3 times larger than